Product ID:2981-99993; SUPERPAINT INTERIOR SEMI-GLOSS LATEX (SUPDAT)
MSDS Date:05/18/1999
FSC:8010
NIIN:00N092195
Status Code:A
MSDS Number: CJRNC

SHERWIN-WILLIAMS COMPANY

101 PROSPECT AVE N W
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

0.06

CAS: 112-34-5

RTECS: KJ9100000

0.12

CAS: 107-21-1

RTECS: KW2975000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: FF9335000

OSHA PEL 15 (5) MG/M3 DUST

ACGIH TLV: 10 MG/M3 DUST

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ROUTES OF EXPOSURE: EXPOSURE MAY BE BY
INHALATION AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF
USE. TO MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE,
VENTILATION, AND PERSONAL PRO TECTIVE EQUIPMENT. ACUTE: IRRITATION
OF EYES, SKIN AND UPPER RESPIRATORY SYSTEM. IN A CONFINED AREA
VAPORS IN HIGH CONCENTRATION MAY CAUSE HEADACHE, NAUSEA OR
DIZZINESS. SIGNS AND SYMPTOMS OF OVEREXPO SURE: REDNESS AND ITCHING
OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
CHRONIC: ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS
BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS AND MICE AT HIGH (EFTS
OF OVEREXP)
Effects of Overexposure:HLTH HAZ: DOSE WHEN GIVEN IN DRINKING WATER OR
BY GAVAGE. THERE IS NO EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS
IN HUMANS. PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION
2 MAY CAUSE ADVER SE EFFECTS TO THE LIVER AND URINARY SYSTEMS. RATS
EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG
CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE
WORKPLACE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY
WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE RE-USE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL
ATTENTION.

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRESSUR E BUILD-UP AND POSSIBLE AUTOIGNITION OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. HMIS CODES:
HEALTH 2, FLAMMABILITY: 0, REACTIVITY: 0.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:DOL STORAGE CATEGORY: NOT APPLICABLE.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED
CONTAINERS WITHCOMPLETE AND APPROPRIATE LABELING. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH O F CHILDREN.
Other Precautions:PRECS TO BE TAKEN IN USE: USE ONLY W/ADEQUATE VENT.
AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. THIS
COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED
"AS DUST" IN SECTIO N 2) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY
DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC D USTS ARE
(SUPDAT)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATLS IN SECIOTON 2. WHEN SANDING /ABRADING DRIED FILM,
WEAR DUST/MIST RESP APPROVED BY NIOSH FOR DUST WHICH MAY BE
GENERATED FROM THIS PRODUCT, UNDERLYING PAINT/APRASIVE.
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS TO
MATLS IN SECTION 2 IS MAINTAINED BELOW APPLIC EXPOSE LIM. REFER TO
OSHA STD 1910.94,1910.107, 1910.108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #:ENAMEL PURE WHITE X. PHYSICAL DATA:VOC
(THEORETICAL): 1.22 LB 146 GM. (LESS FED EXEMPT SOLVS).PROD WT:
10.76 LB/GAL.OTHER PREC: LISTED IN SEC 2, APPLIC LIMITS FOR
NUISANCE DUST S ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESP
FRACTION), OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESP FRACTION).

Boiling Pt:>100.C, 212.F
B.P. Text:212-448F
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Spec Gravity:1.29
VOC Pounds/Gallon:146
pH:9.5
VOC Grams/Liter:1.22
Evaporation Rate & Reference:SLOWER HAN ETHER
Appearance and Odor:PURE WHITE BASE X.
Percent Volatiles by Volume:60

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:WASTE FROM THIS PRODUCT IS NOT HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED
CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL
REGULATIONS REGARDING POLLUTION.

SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION: CAS NO: 107-21-1 CHEMICAL/COMPOUND: ETHYLENE GLYCOL.
% BY WT: 3 CHEMICAL/COMPOUND: GLYCOL ETHERS: % BY WT: 2.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.